Cov tshuaj cholorine yog tsim los ntawm cov dej ntsev hluav taws xob hauv tshuab hluav taws xob.Kev yug ntawm electrolysis tuaj yeem taug qab mus rau 1833. Faraday pom ntawm cov kev sim hluav taws xob uas thaum muaj roj av sodium, tshuaj chlorine tau txais. Cov tshuaj tiv thaiv cov tshuaj tiv thaiv yog:

2NaNkl + 2H₂o == 2Nsoh + h₂↑ + CLR

Tom qab, British tus kws tshawb fawb Watt kuj tau pom cov qauv no thiab tau txais ib qho patent hauv xyoo 1851 rau kev tsim cov tshuaj chlorine. Txawm li cas los xij, vim qhov tsis muaj cov khoom siv hluav taws xob ua tau zoo tam sim no lub sijhawm ntawd, cov qauv electrolysis yuav tuaj yeem nyob rau hauv chav kuaj thiab tsis tuaj yeem muab tso rau hauv kev lag luam lag luam, yog li tau muab tso rau hauv kev lag luam. Nws tsis tau txog thaum xyoo 1870s rau 1980s uas zoo DC cov tshuab hluav taws xob tawm thiab electrolysis tsis tau siv dav. Txij ntawd los, kev lag luam tsim cov tshuaj chlorine roj nkag mus rau lub sijhawm tshiab. Txawm li cas los xij, lub sijhawm ntawd, cov electrode siv rau kev tsim cov tshuaj electrolysis kom muaj mercury, ua rau muaj cov tshuaj mercury sib xyaw thiab hydrogen roj tau txais los ntawm electrolysis. Qhov "Mercury raws chlorine txoj kev" poses zoo nkauj ib puag ncig kev nyab xeeb "rau kev ua kom zoo nkauj roj maub yog ib puag ncig zoo dua thiab txuag hluav taws xob. Mercury raws chlorine ntau lawm yog txoj kev pom kev zoo rau kev ua cov tshuaj chlorine. Piv txwv li, xyoo 2010, Tuam Tshoj muaj 46% ntawm cov tshuaj chlorine, thiab hauv 2000, 50.1 ntawm cov tshuaj chlorine roj nyob rau sab hnub poob Europe tau tsim kev siv hom no.

Chlorine roj yog kojsed rau kev kho dej rau kev ua haujlwm hauv kev ua haujlwm ua haujlwm, Tshuaj tua kab mob ntawm cov kais dej, Tshem cov leej faj thiab phosphorus impurities los ntawm acetylene, Raws li cov khoom siv raw rau kev ua cov tshuaj tua kab ua tau zoo, fungicides, tshuaj ntsuab, thiab cov nroj tsuag loj hlob stimulantshauv tNws Kev Lag Luam Tshuaj Lom, thiab cov tshuaj lis dej num pa roj av kuj tau siv rau hauv tNws ntxub kev lag luam feem ntau yog siv rau kev tsim cov hlau me xws li titanium thiab magnesium.

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